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(In the original Woodward and Hoffmann book, the example is
predicated on the transformation of the sp2 terminal hybrids to
sp3 hybrids, so that
bonds could be formed between atoms
1 and 4. We choose instead to leave the hybridization alone and allow
these terminal carbon atoms to bond using
orbitals.
Only the
symmetry considerations matter, so our approach is good enough.
In our simplified approach, we use pz orbitals to form
orbitals).
In both cases, the 1-2 and the 3-4 ``
'' bonds are broken, a 2-3 ``
'' bond
forms, and a 1-4 bond forms (
)
(
and
).
Carl David
1999-06-16